翻訳と辞書 Words near each other ・ Trigon (Ditson) ・ Trigon (game) ・ Trigon (German band) ・ Trigon (Moldovan band) ・ Trigon Bluff ・ Trigon puzzle ・ Trigona (genus) ・ Trigona (Tetragonula) ・ Trigona collina ・ Trigona corvina ・ Trigona fulviventris ・ Trigona fuscipennis ・ Trigona hockingsi ・ Trigona spinipes ・ Trigonachras ・ Trigonal bipyramidal molecular geometry ・ Trigonal crystal system ・ Trigonal planar molecular geometry ・ Trigonal prismatic molecular geometry ・ Trigonal pyramidal molecular geometry ・ Trigonal trapezohedral honeycomb ・ Trigonal trapezohedron ・ Trigonalidae ・ Trigonaphera ・ Trigonaphera amakusana ・ Trigonaphera bocageana ・ Trigonaphera stenomphala ・ Trigonarthris ・ Trigone ・ Trigone of urinary bladder Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Trigonal bipyramidal molecular geometry ： ウィキペディア英語版 Trigonal bipyramidal molecular geometry In chemistry a trigonal bipyramid formation is a molecular geometry with one atom at the center and 5 more atoms at the corners of a triangular dipyramid. This is one geometry for which the bond angles surrounding the central atom atom are not identical (see also pentagonal dipyramid), because there is no geometrical arrangement with five terminal atoms in equivalent positions. Examples of this molecular geometry are phosphorus pentafluoride (PF5), and phosphorus pentachloride (PCl5) in the gas phase. ==Axial and equatorial positions== The five atoms bonded to the central atom are not all equivalent, and two different types of position are defined. For phosphorus pentachloride as an example, the phosphorus atom shares a plane with three chlorine atoms at 120 degree angles to each other in ''equatorial'' positions, and two more chlorine atoms above and below the plane (''axial'' or ''apical'' positions). According to the VSEPR theory of molecular geometry, an axial position is more crowded because an axial atom has three neighboring equatorial atoms (on the same central atom) at a 90° bond angle, whereas an equatorial atom has only two neighboring axial atoms at a 90° bond angle. For molecules with five identical ligands, the axial bond lengths tend to be longer because the ligand atom cannot approach the central atom as closely. As examples, in PF5 the axial P−F bond length is 158 pm and the equatorial is 152 pm, and in PCl5 the axial and equatorial are 214 and 202 pm respectively.〔 In the mixed halide PF3Cl2 the chlorines occupy two of the equatorial positions,〔 indicating that fluorine has a greater apicophilicity or tendency to occupy an axial position. In general ligand apicophilicity increases with electronegativity and also with pi-electron withdrawing ability, as in the sequence Cl < F < CN.〔(Apicophilicity ) IUPAC Gold Book or Compendium of Chemical Terminology〕 Both factors decrease electron density in the bonding region near the central atom so that crowding in the axial position is less important. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Trigonal bipyramidal molecular geometry」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.